- Categories
- Shape-Independent
- broad-peak (SASfit)
- sasfit_broad_peak.py
broad-peak (SASfit) - sasfit_broad_peak.py
r"""
This file has been automatically generated by sasfit_convert and manually edited
by Wojciech Potrzebowski, ESS on 2017-12-05.
The model calculates an empirical functional form for SAS data characterized
by broad_peak (as defined in SASFit)
Definition:
-----------
Many SANS spectra are characterized by a broad peak even though they are
from amorphous soft materials.
The d-spacing corresponding to the broad peak is a characteristic distance
between the scattering inhomogeneities (such as in lamellar, cylindrical,
or spherical morphologies or for bicontinuous structures).
The following simple functional form reproduces the broad peak feature:
.. math:: I(q) = frac{I_0}{({1 + (|q - q_0|xi)^m})^p}
Here the peak position is related to the d-spacing as $q_0 = 2pi d$.
Soft systems that show a SANS peak include copolymers, polyelectrolytes,
multiphase systems, layered structures, etc.
.. note::
For $q0 = 0$, $m = 2$ and $p = 1$ one gets the Ornstein-Zernike model.
For $q0 = 0$, $m = 2$ and $p = 2$ The Broad-Peak model is identical to the
Debye-Anderson-Brumberger model.
For 2D data the scattering intensity is calculated in the same way as 1D,
where the $q$ vector is defined as
.. math:: q = sqrt{q_x^2 + q_y^2}
References:
-----------
https://github.com/SASfit/SASfit/
Original SASfit file: /src/plugins/non_particulate/sasfit_ff_broad_peak.c
A paper about SASfit has been published in
J. Appl. Cryst. (2015). 48, 1587-1598
doi:10.1107/S1600576715016544
"""
from numpy import inf
name = "broad_peak"
title = " "
description = """
F^2(q,I0,xi,m,q0) = I0/(1+(|q-q0|*xi)^m)^p
List of default parameters
I0: forward scattering
xi: correlation length
q0:peak position which is related to the d-spacing as q0 = 2pi/d
m: exponent m
p: exponnent p
"""
category = "shape-independent"
#pylint: disable=bad-whitespace, line-too-long
parameters = [
["I0", "", 10.0, [-inf, inf], "", "forward scattering"],
["XI", "Ang", 50.0, [-inf, inf], "", "correlation length"],
["Q0", "1/Ang", 0.01, [-inf, inf], "", "peak position which is related to the d-spacing as q0 = 2pi/d"],
["M", "", 2.0, [-inf, inf], "", "exponent m"],
["P", "", 1.0, [-inf, inf], "", "exponnet p"],
]
#pylint: enable=bad-whitespace, line-too-long
source = ["sasfit_broad_peak.c"]
demo = {
"I0" : 10.0,
"XI" : 50.0,
"Q0" : 0.01,
"M" : 2.0,
"P" : 1.0
}
tests = [[{}, 0.001, 8.31700831601],
[{'P':2}, 0.001, 6.91659943119],
[{}, 0.2, 0.110589041096],
[{'Q0':0.2}, 0.2, 10.001],
[{}, [0.2], [0.110589041096]]
]
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